GB/T 4698.21-2019 English PDF (GB/T4698.21-2019)

GB/T 4698.21-2019: Methods for chemical analysis of titanium sponge, titanium and titanium alloys - Part 21: Determination of manganese, chromium, nickel, aluminum, molybdenum, tin, vanadium, yttrium, copper and zirconium content - Atomic emission spectrometry
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GB/T 4698.21-2019
NATIONAL STANDARD OF THE
PEOPLE’S REPUBLIC OF CHINA
ICS 77.120.50
H 14
Replacing GB/T 4698.21-1996
Methods for chemical analysis of titanium sponge,
titanium and titanium alloys -- Part 21: Determination
of manganese, chromium, nickel, aluminum,
molybdenum, tin, vanadium, yttrium, copper and
zirconium content - Atomic emission spectrometry
ISSUED ON: JUNE 04, 2019
IMPLEMENTED ON: MAY 01, 2020
Issued by: State Administration for Market Regulation;
Standardization Administration of the People's Republic of
China.
Table of Contents
Foreword ... 3 
1 Scope ... 7 
2 Normative references ... 7 
3 Principle ... 8 
4 Reagents ... 8 
5 Equipment ... 8 
6 Sample ... 9 
7 Test steps ... 9 
8 Precision ... 11 
9 Test report ... 12 
Foreword
GB/T 4698 “Methods for chemical analysis of titanium sponge, titanium and
titanium alloys” consists of the following parts:
-- Part 1: Determination of copper content - Flame atomic absorption
spectrometry;
-- Part 2: Determination of iron content;
-- Part 3: Determination of silicon content - Molybdenum blue
spectrophotometry;
-- Part 4: Determination of manganese content-Potassium periodate
spectrophotometry and inductively coupled plasma atomic emission
spectrometry;
-- Part 5: Determination of molybdenum content - Thiocyanate
spectrophotometry and inductively coupled plasma atomic emission
spectrometry;
-- Part 6: Determination of boron content - Methylene blue spectrophotometry
and inductively coupled plasma atomic emission spectrometry;
-- Part 7: Determination of oxygen and nitrogen content;
-- Part 8: Determination of aluminum content - Separation with sodium
hydroxide-EDTA complex-metric titration and inductively coupled plasma
atomic emission spectrometry;
-- Part 9: Determination of tin content - Potassium iodate titration and
inductively coupled plasma atomic emission spectrometry;
-- Part 10: Determination of chromium content - Ammonium ferrous sulfate
titration and inductively coupled plasma atomic emission spectrometry
(with vanadium;
-- Part 11: Determination of chromium content in the absence of Vanadium -
Ammonium ferrous sulfate titration method;
-- Part 12: Determination of vanadium content - Ammonium ferrous sulfate
titration and inductively coupled plasma atomic emission spectrometry;
-- Part 13: Determination of zirconium content - EDTA complexometric
titration and inductively coupled plasma atomic emission spectrometry;
-- Part 14: Determination of carbon content;
This Part is Part 21 of GB/T 4698.
This Part was drafted in accordance with the rules given in GB/T 1.1-2009.
This Part replaces GB/T 4698.21-1996 “Sponge titanium, titanium and titanium
alloys-Determination of manganese, chromium, nickel, aluminum, molybdenum,
tin, vanadium, yttrium, copper, zirconium content-Emission spectrographic
method”. Compared with GB/T 4698.21-1996, in addition to editorial
modifications, the main technical changes are as follows:
- modified the determination range: Mn, Cr, Ni from 0.02%~0.20%, Al, Mo,
Sn, V, Y and Zr from 0.01%~0.15%, Cu from 0.001%~0.015% to
0.0005%~0.050% (see Clause 1 of this Edition, Clause 1 of Edition 1996);
- modified the normative references (see Clause 2 of this Edition, Clause 2
of Edition 1996);
- buffer was modified from toner to silver chloride-graphite buffer; re-
described the method principle (see Clause 3 of this Edition, Clause 3 of
Edition 1996);
- modified the equipment, added “graphite electrode structure and
dimensions” (see Clause 5 of this Edition, Clause 5 of Edition 1996);
- added the requirements for sample (see Clause 6);
- modified the method for preparing spectrum sample (see 7.2 of this Edition,
6.2 of Edition 1996);
- modified the standard sample preparation, determination conditions and
measurement methods (see 7.3 of this Edition, 6.3 of Edition 1996);
- deleted the description for analysis results (see Clause 7 of Edition 1996);
- added the sub-clauses on precision (see Clause 8 of this Edition);
- added the sub-clauses on test report (see Clause 9 of this Edition).
This Part was proposed by China Nonferrous Metals Industry Association.
This Part shall be under the jurisdiction of National Technical Committee on
Non-ferrous Metals of Standardization Administration of China (SAC/TC 243).
The drafting organizations of this Part: Northwest Nonferrous Metal Research
Institute, National Standard (Beijing) Inspection and Certification Co., Ltd.,
Ningxia Dongfang Tantalum Co., Ltd., Jinchuan Group Co., Ltd.
Main drafters of this Part: Zhou Kai, Ma Xiaomin, Sun Baolian, Wei Hongnan,
Zhang Renhui, Mo Shumin, Fu Jianguo, Wang Changhua, Qiu Ping.
Methods for chemical analysis of titanium sponge,
titanium and titanium alloys -- Part 21: Determination
of manganese, chromium, nickel, aluminum,
molybdenum, tin, vanadium, yttrium, copper and
zirconium content - Atomic emission spectrometry
1 Scope
This Part of GB/T 4698 specifies the determination method for manganese,
chromium, nickel, aluminum, molybdenum, tin, vanadium, yttrium, copper and
zirconium content in titanium sponge, titanium and titanium alloys.
This Part is applicable to the determination of manganese, chromium, nickel,
aluminum, molybdenum, tin, vanadium, yttrium, copper and zirconium content
in titanium sponge, titanium and titanium alloys. See Table 1 for the
determination range.
Table 1 -- Elements and determination range
2 Normative references
The following referenced documents are indispensable for the application of
this document. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any
amendments) applies.
GB/T 31981, Methods of sampling and sample preparation for chemical
composition analysis of titanium and titanium alloy
3 Principle
Use hydrochloric acid to dissolve test material. Evaporate to dryness. Burn to
oxide. Grind into powder and mix with a certain amount of buffer (silver chloride
+ carbon powder). Use atomic emission spectrometer arc excitation for sample
analysis. According to the working curve, calculate the content of each impurity
element.
4 Reagents
4.1 Titanium oxide (titanium oxide mass fraction ≥99.995%).
4.2 Manganese oxide, spectrally pure.
4.3 Chromium oxide, spectrally pure.
4.4 Nickel oxide, spectrally pure.
4.5 Alumina, spectrally pure.
4.6 Molybdenum oxide, spectrally pure.
4.7 Tin oxide, spectrally pure.
4.8 Vanadium oxide, spectrally pure.
4.9 Yttrium oxide, spectrally pure.
4.10 Copper oxide, spectrally pure.
4.11 Zirconia, spectrally pure.
4.12 Hydrochloric acid (ρ = 1.19g/mL), guaranteed reagent.
4.13 Graphite powder, spectrally pure.
4.14 Silver chloride, analytical reagent.
4.15 Buffer: weigh an appropriate amount of silver chloride (4.14) and graphite
powder (4.13) at a ratio of 85:15 to mix and grind evenly.
5 Equipment
5.1 DC Arc Atomic Emission Spectrometer.
5.2 Box resistance furnace.
GB/T 4698.21-2019
NATIONAL STANDARD OF THE
PEOPLE’S REPUBLIC OF CHINA
ICS 77.120.50
H 14
Replacing GB/T 4698.21-1996
Methods for chemical analysis of titanium sponge,
titanium and titanium alloys -- Part 21: Determination
of manganese, chromium, nickel, aluminum,
molybdenum, tin, vanadium, yttrium, copper and
zirconium content - Atomic emission spectrometry
ISSUED ON: JUNE 04, 2019
IMPLEMENTED ON: MAY 01, 2020
Issued by: State Administration for Market Regulation;
Standardization Administration of the People's Republic of
China.
Table of Contents
Foreword ... 3 
1 Scope ... 7 
2 Normative references ... 7 
3 Principle ... 8 
4 Reagents ... 8 
5 Equipment ... 8 
6 Sample ... 9 
7 Test steps ... 9 
8 Precision ... 11 
9 Test report ... 12 
Foreword
GB/T 4698 “Methods for chemical analysis of titanium sponge, titanium and
titanium alloys” consists of the following parts:
-- Part 1: Determination of copper content - Flame atomic absorption
spectrometry;
-- Part 2: Determination of iron content;
-- Part 3: Determination of silicon content - Molybdenum blue
spectrophotometry;
-- Part 4: Determination of manganese content-Potassium periodate
spectrophotometry and inductively coupled plasma atomic emission
spectrometry;
-- Part 5: Determination of molybdenum content - Thiocyanate
spectrophotometry and inductively coupled plasma atomic emission
spectrometry;
-- Part 6: Determination of boron content - Methylene blue spectrophotometry
and inductively coupled plasma atomic emission spectrometry;
-- Part 7: Determination of oxygen and nitrogen content;
-- Part 8: Determination of aluminum content - Separation with sodium
hydroxide-EDTA complex-metric titration and inductively coupled plasma
atomic emission spectrometry;
-- Part 9: Determination of tin content - Potassium iodate titration and
inductively coupled plasma atomic emission spectrometry;
-- Part 10: Determination of chromium content - Ammonium ferrous sulfate
titration and inductively coupled plasma atomic emission spectrometry
(with vanadium;
-- Part 11: Determination of chromium content in the absence of Vanadium -
Ammonium ferrous sulfate titration method;
-- Part 12: Determination of vanadium content - Ammonium ferrous sulfate
titration and inductively coupled plasma atomic emission spectrometry;
-- Part 13: Determination of zirconium content - EDTA complexometric
titration and inductively coupled plasma atomic emission spectrometry;
-- Part 14: Determination of carbon content;
This Part is Part 21 of GB/T 4698.
This Part was drafted in accordance with the rules given in GB/T 1.1-2009.
This Part replaces GB/T 4698.21-1996 “Sponge titanium, titanium and titanium
alloys-Determination of manganese, chromium, nickel, aluminum, molybdenum,
tin, vanadium, yttrium, copper, zirconium content-Emission spectrographic
method”. Compared with GB/T 4698.21-1996, in addition to editorial
modifications, the main technical changes are as follows:
- modified the determination range: Mn, Cr, Ni from 0.02%~0.20%, Al, Mo,
Sn, V, Y and Zr from 0.01%~0.15%, Cu from 0.001%~0.015% to
0.0005%~0.050% (see Clause 1 of this Edition, Clause 1 of Edition 1996);
- modified the normative references (see Clause 2 of this Edition, Clause 2
of Edition 1996);
- buffer was modified from toner to silver chloride-graphite buffer; re-
described the method principle (see Clause 3 of this Edition, Clause 3 of
Edition 1996);
- modified the equipment, added “graphite electrode structure and
dimensions” (see Clause 5 of this Edition, Clause 5 of Edition 1996);
- added the requirements for sample (see Clause 6);
- modified the method for preparing spectrum sample (see 7.2 of this Edition,
6.2 of Edition 1996);
- modified the standard sample preparation, determination conditions and
measurement methods (see 7.3 of this Edition, 6.3 of Edition 1996);
- deleted the description for analysis results (see Clause 7 of Edition 1996);
- added the sub-clauses on precision (see Clause 8 of this Edition);
- added the sub-clauses on test report (see Clause 9 of this Edition).
This Part was proposed by China Nonferrous Metals Industry Association.
This Part shall be under the jurisdiction of National Technical Committee on
Non-ferrous Metals of Standardization Administration of China (SAC/TC 243).
The drafting organizations of this Part: Northwest Nonferrous Metal Research
Institute, National Standard (Beijing) Inspection and Certification Co., Ltd.,
Ningxia Dongfang Tantalum Co., Ltd., Jinchuan Group Co., Ltd.
Main drafters of this Part: Zhou Kai, Ma Xiaomin, Sun Baolian, Wei Hongnan,
Zhang Renhui, Mo Shumin, Fu Jianguo, Wang Changhua, Qiu Ping.
Methods for chemical analysis of titanium sponge,
titanium and titanium alloys -- Part 21: Determination
of manganese, chromium, nickel, aluminum,
molybdenum, tin, vanadium, yttrium, copper and
zirconium content - Atomic emission spectrometry
1 Scope
This Part of GB/T 4698 specifies the determination method for manganese,
chromium, nickel, aluminum, molybdenum, tin, vanadium, yttrium, copper and
zirconium content in titanium sponge, titanium and titanium alloys.
This Part is applicable to the determination of manganese, chromium, nickel,
aluminum, molybdenum, tin, vanadium, yttrium, copper and zirconium content
in titanium sponge, titanium and titanium alloys. See Table 1 for the
determination range.
Table 1 -- Elements and determination range
2 Normative references
The following referenced documents are indispensable for the application of
this document. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any
amendments) applies.
GB/T 31981, Methods of sampling and sample preparation for chemical
composition analysis of titanium and titanium alloy
3 Principle
Use hydrochloric acid to dissolve test material. Evaporate to dryness. Burn to
oxide. Grind into powder and mix with a certain amount of buffer (silver chloride
+ carbon powder). Use atomic emission spectrometer arc excitation for sample
analysis. According to the working curve, calculate the content of each impurity
element.
4 Reagents
4.1 Titanium oxide (titanium oxide mass fraction ≥99.995%).
4.2 Manganese oxide, spectrally pure.
4.3 Chromium oxide, spectrally pure.
4.4 Nickel oxide, spectrally pure.
4.5 Alumina, spectrally pure.
4.6 Molybdenum oxide, spectrally pure.
4.7 Tin oxide, spectrally pure.
4.8 Vanadium oxide, spectrally pure.
4.9 Yttrium oxide, spectrally pure.
4.10 Copper oxide, spectrally pure.
4.11 Zirconia, spectrally pure.
4.12 Hydrochloric acid (ρ = 1.19g/mL), guaranteed reagent.
4.13 Graphite powder, spectrally pure.
4.14 Silver chloride, analytical reagent.
4.15 Buffer: weigh an appropriate amount of silver chloride (4....