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GB/T 11064.5-2013 English PDF (GBT11064.5-2013)

GB/T 11064.5-2013 English PDF (GBT11064.5-2013)

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GB/T 11064.5-2013: Methods for chemical analysis of lithium carbonate, lithium hydroxide monohydrate and lithium chloride -- Part 5: Determination of calcium content -- Flame atomic absorption spectrometric method

This Part of GB/T 11064 specifies the determination method of calcium in lithium carbonate, in lithium hydroxide monohydrate, and in lithium chloride. This Part applies to the determination of calcium in lithium carbonate, in lithium hydroxide monohydrate, and in lithium chloride. The determination range: 0.0020%~0.35%.
GB/T 11064.5-2013
GB
NATIONAL STANDARD OF THE
PEOPLE REPUBLIC OF CHINA
ICS 77.120.99
H 64
Replacing GB/T 11064.5-1989
Methods for chemical analysis of lithium carbonate,
lithium hydroxide monohydrate and lithium chloride -
Part 5. Determination of calcium content -
Flame atomic absorption spectrometric method
ISSUED ON. NOVEMBER 27, 2013
IMPLEMENTED ON. AUGUST 01, 2014
Issued by.
General Administration of Quality Supervision, Inspection
and Quarantine of the PEOPLE Republic of China;
Standardization Administration of the PEOPLE Republic of
China.
Table of Contents
Foreword ... 3
1 Scope ... 5
2 Method summary ... 5
3 Reagents... 5
4 Apparatus ... 6
5 Samples ... 6
6 Analysis steps ... 7
7 Calculation of analysis results ... 8
8 Precision ... 8
9 Test report ... 9
Foreword
GB/T 11064 ?€?Methods for chemical analysis of lithium carbonate, lithium hydroxide monohydrate and lithium chloride?€? is divided into 16 parts.
- Part 1. Determination of lithium carbonate content - Acid-alkali titrimetric method; - Part 2. Determination of lithium hydroxide content - Acid-alkali titrimetric method; - Part 3. Determination of lithium chloride content - Potentiometric method; - Part 4. Determination of potassium and sodium content - Flame atomic
absorption spectrometric method;
- Part 5. Determination of calcium content - Flame atomic absorption spectrometric method;
- Part 6. Determination of magnesium content - Flame atomic absorption
spectrometric method;
- Part 7. Determination of iron content - 1,10-phenanthroline spectrophotometric method;
- Part 8. Determination of silicon content - Molybdenum blue spectrophotometric method;
- Part 9. Determination of sulfate content - Barium sulfate nephelometry method; - Part 10. Determination of chloride content - Silver chloride nephelometry method; - Part 11. Determination of Acid-insolubles Content - Gravimetric method; - Part 12. Determination of carbonate content - Determination of lithium chloride content - Potentiometric method;
- Part 13. Determination of aluminum content - Chromazurol S-cetylpyridine bromide spectrophotometric method;
- Part 14. Determination of arsenic content - Molybdenum blue spectrophotometric method;
- Part 15. Determination of fluoride content - Ion selective method;
- Part 16. Determination of calcium, magnesium, copper, lead, zinc, nickel, manganese, cadmium and aluminum content - Inductively coupled plasma
atomic emission spectrometry.
This Part is part 5 of GB/T 11064.
This Part is drafted in accordance with rules given in GB/T 1.1-2009.
The Part replaces GB/T 11064.5-1989 "Methods for chemical analysis of lithium carbonate, lithium hydroxide monohydrate and lithium chloride - Part 5. Determination of calcium content - Flame atomic absorption spectrometric method".
Compared with GB/T 11064.5-1989, the main changes of this Part are as follows. - REVISE the determination range ?€?0.0060%~0.350%?€? to be ?€?0.0020%~0.35%?€?; - REVISE ?€?add 5mL of citric acid solution?€? to be ?€?add 1mL of citric acid solution?€?; - ADD the repeatability terms;
- RE-EDIT the text format; ADD the test report.
This Part shall be under the jurisdiction of National Standardization Technical Committee of Nonferrous Metals (SAC/TC 243).
Drafting organizations of this Part. Xinjiang Wuxin Lithium Salt Development Co., Ltd., Ganzhou Nonferrous Metallurgy Research Institute, and Haimen Ronghui General Lithium Industry Co., Ltd.
The main drafters of this Part. Guan Yuzhen, Zhao Fanglan, Lai Jian, Liu Hong, Deng Hongyun, Chen Xian?€?an, and Liu Yan.
The historical version replaced by this Part is as follows.
- GB/T 11064.5-1989.
Methods for chemical analysis of lithium carbonate,
lithium hydroxide monohydrate and lithium chloride -
Part 5. Determination of calcium content -
Flame atomic absorption spectrometric method
1 Scope
This Part of GB/T 11064 specifies the determination method of calcium in lithium carbonate, in lithium hydroxide monohydrate, and in lithium chloride.
This Part applies to the determination of calcium in lithium carbonate, in lithium hydroxide monohydrate, and in lithium chloride. The determination range. 0.0020%~0.35%.
2 Method summary
The lithium carbonate and lithium hydroxide samples are dissolved in hydrochloric acid; lithium chloride sample is dissolved in water. In the dilute hydrochloric acid medium, at wavelength of 422.7nm on atomic absorption spectrometer, use lanthanum salt and citric acid as release agent, use air - acetylene flame and standard addition method to determine it.
3 Reagents
Unless otherwise indicated, all reagents used in this Part are guaranteed reagent, the water used is deionized water.
3.1 Hydrochloric acid (1+1).
3.2 Lanthanum salt solution. weigh 5.864g of lanthanum oxide [ %9.99)( 32 ???OLaw ]; place them in a 100mL beaker; add hydrochloric acid to dissolve and make it clear (heat it if necessary); transfer them in 500mL flask; use water to dilute to scale; shake well. 1mL of this solution contains 10mg of lanthanum.
3.3 Citric acid solution (100g/L). weigh 50g of citric acid; place in a 500mL beaker; add 500mL of water to dissolve; use hydrogen-type cation exchange resin to purify. 3.4 Calcium standard stock solution. weigh 2.4972g of calcium carbonate The difference of analysis results among laboratories shall not be more than the allowable difference in Table 3.
Table 3
Mass fraction of calcium/% Allowable difference/%
0.0020~0.0060 0.0004
>0.0060~0.010 0.004
>0.010~0.050 0.006
>0.050~0.10 0.01
>0.10~0.35 0.03
9 Test report
The test report shall contain the following content.
- Sample;
- The number of this Part national standard;
- Analysis result and its expression;
- Difference with the basic analysis step;
- Anomalies observed in the determination;
- Determination date.

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