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GB 30000.17-2013: Rules for classification and labelling of chemicals -- Part 17: Corrosive to metals
GB 30000.17-2013
Rules for classification and labelling of chemicals - Part 17. Corrosive to metals
ICS 13.300
A80
National Standards of People's Republic of China
Replacing GB 20588-2006
Chemical classification and labeling specifications
Part 17. metal corrosion
Issued on. 2013-10-10
2014-11-01 implementation
Administration of Quality Supervision, Inspection and Quarantine of People's Republic of China
Standardization Administration of China released
Foreword
Part 4, Chapter 6 are mandatory, the rest are recommended.
GB 30000 "chemical classification and labeling norms," the expected structure and national standards will be replaced as follows.
--- Part 1. General (instead of GB 13690-2009);
--- Part 2. Explosives (instead of GB 20576-2006);
--- Part 3. flammable gases (instead of GB 20577-2006);
--- Part 4. Aerosol (instead of GB 20578-2006);
--- Part 5. oxidizing gas (instead of GB 20579-2006);
--- Part 6. pressurized gas (instead of GB 20580-2006);
--- Part 7. flammable liquids (instead of GB 20581-2006);
--- Part 8. Flammable solids (instead of GB 20582-2006);
--- Part 9. Self-reactive substances and mixtures (instead of GB 20583-2006);
--- Part 10. Pyrophoric liquids (instead of GB 20585-2006);
--- Part 11. Spontaneous solid (instead of GB 20586-2006);
--- Part 12. Self-heating substances and mixtures (instead of GB 20584-2006);
--- Part 13. water, emit flammable gases and mixtures (instead of GB 20587-2006);
--- Part 14. oxidizing liquid (instead of GB 20589-2006);
--- Part 15. oxidizing solids (instead of GB 20590-2006);
--- Part 16. Organic peroxide (instead of GB 20591-2006);
--- Part 17. metallic corrosion products (instead of GB 20588-2006);
--- Part 18. Acute toxicity (instead of GB 20592-2006);
--- Section 19. Skin corrosion/irritation (instead of GB 20593-2006);
--- Part 20. Serious eye damage/eye irritation (instead of GB 20594-2006);
--- Part 21. respiratory or skin sensitization (instead of GB 20595-2006);
--- Part 22. germ cell mutagenicity (instead of GB 20596-2006);
--- Part 23. carcinogenic (instead of GB 20597-2006);
--- Part 24. Reproductive toxicity (instead of GB 20598-2006);
--- Part 25. Specific target organ toxicity - single exposure (instead of GB 20599-2006);
--- Part 26. Specific target organ toxicity, repeated exposure (instead of GB 20601-2006);
--- Part 27. Inhalation Hazard;
--- Part 28. harmful to the aquatic environment (instead of GB 20602-2006);
--- Part 29. harmful to the ozone layer;
--- Part 30. Chemical workplace warning signs;
This is Part 17 GB 30000's.
This section drafted in accordance with GB/T 1.1-2009 given rules.
This Part replaces GB 20588-2006 "chemical classification, precautionary labeling and precautionary statements of specification metal corrosion."
This part of the United Nations' Globally Harmonized System of Classification and Labelling "(Globaly HarmonizedSystem of
ClassificationandLabelingofChemicals, GHS) (fourth revised edition) about the technical content of the same.
This section compared with GB 20588-2006, the major technical changes as follows.
--- Modify the standard name, Chinese name was changed to "classification and labeling of chemicals - Part 17. metal corrosion," the English name
Called "Rulesforclassificationandlabelingofchemicals-Part 17. Corrosivetometals";
--- Modify the scope of content Chapter 1, the "warning labels" to "tag" Delete "precautionary statements";
--- Revised Chapter 2, "Normative references" the key words, and added, "the United Nations' Globally Harmonized System of Classification and Labelling
Degree "(fourth revised edition)" is a reference document;
--- Increased Chapter 3, "Terms and definitions" in the introductory phrase;
--- FIG Chapter 5 1 "decision logic diagram" and "guidance" as informative Appendix A;
--- Deleted the original Chapter 7, according to the United Nations' Globally Harmonized System of Classification and Labelling "(fourth revised edition) Chapter 7 of the original
Table 3 modification as a normative appendix B;
--- According to the United Nations' Globally Harmonized System of Classification and Labelling "(fourth revised edition) original Chapter 6, Chapter 7, Chapter 8 modify the whole
Synthesis Chapter 6; Table 2 original and modified as a normative Annex C;
--- Deleted the original Chapter 8, "hazard statements" and the related "precautionary statements" content as informative annex D;
--- Added "example of the label" informative appendix E.
This part of the National Chemicals Management Standardization Technical Committee dangerous (SAC/TC251) and focal points.
This section is drafted. Beijing Entry-Exit Inspection and Quarantine Bureau, Sichuan dangerous chemicals quality supervision, inspection, Huafeng Group Limited.
The main drafters of this section. Tangshu Tian, Wang Dan, Hou Ying, Wang Juan, Chenqing Jun, Xie Muwen, Manning, He Ying Oriole, Zhangqi Bin, Li Xiaofeng.
This part of the alternative criteria previously issued as follows.
--- GB 20588-2006.
Chemical classification and labeling specifications
Part 17. metal corrosion
1 Scope
This part of GB 30000 specifies the terms and definitions of metal corrosion, classification criteria, decision logic and guidance label.
This section applies to metallic corrosion by the United Nations' Globally Harmonized System of Classification and Labelling "(hereinafter referred to as the GHS) of Classification and
label.
2 Normative references
The following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein
Member. For undated references, the latest edition (including any amendments) applies to this document.
GB/T 700 carbon structural steel
GB 6944-2012 Classification and code of dangerous goods
GB 13690 chemical classification and hazard communication General
GB/T 21621 dangerous metal corrosion test methods
The United Nations' Globally Harmonized System of Classification and Labelling "(fourth revised edition)
United Nations "on the Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth revised Edition)
3 Terms and Definitions
GB 13690 and defined by the following terms and definitions apply to this document.
3.1
Metal corrosion corrosivetometals
By chemical action would significantly damage or even destroy the substance or mixture of metals.
4 Classification Standard
4.1 General principles metallic corrosion classification and labeling see GB 13690.
4.2 Metal corrosion in accordance with GB/T 21621 tested according to Table 1 classification.
Table 1 Classification of metal corrosion
Standard category
1 at a test temperature of 55 ℃, the corrosion rate of steel or aluminum surfaces exceeding 6.25mm per year
NOTE. If the first test on either steel or aluminum indicates, acceptance test of the substance or mixture is corrosive, it is no longer on the other metal
test.
5 decision logic and guidance
Decision logic and guidance purposes only. Decision logic and guidance in Appendix A. Special Recommendations person responsible for classification in use decision logic
Before editing and the use of research in Chapter 4.
6 Label
6.1 Overview
6.1.1 The label of metal corrosion, hazard categories are specified pictograms, signal words and hazard statements the order listed. United Nations
"On Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth revised Edition) (hereinafter referred to as "Model Regulations") covering hazard class or classes
Do not list each category should specify the corresponding graphic logo in the label. Metallic corrosion assigned label elements are shown in Appendix B.
6.1.2 metal corrosion about the criteria for classification and labeling elements in Appendix C.
6.1.3 Requirements on the label information including hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and vendor logo.
Note. For yet other standardized label elements, such as the need to include precautionary statements on the label. Administrations may also ask for additional information, supply
Suppliers may also add supplementary information.
6.2 hazard pictograms
Hazard pictograms should be a black symbol on a white background with a red frame sufficiently wide to be clearly visible.
"Model Regulations" provisions of the hazard pictograms, graphic signs colors, numbers and minimum dimensions given in Appendix B.
6.3 Signal word
Signal word means a label used to indicate the relative severity of the hazard and alert the reader to potentially dangerous words. For metal corrosion
Use the signal word "Warning."
6.4 Hazard statement
Hazard statement means assigned to a hazard class and category of the phrase used to describe the nature of the risk of a dangerous product, in the case when appropriate
Also include the degree of danger. Metal corrosion hazard statements and precautionary statements, see Appendix D.
6.5 Precautionary statements
Precautionary statement is a phrase (and/or pictogram) which describes minimize or prevent exposure to hazardous products or improper
Storage or handling dangerous goods and adverse effects of recommended actions. To meet the requirements, there are five types of precautionary statements. general, prevention should be
Anxious, storage and disposal. Corrosive to metals Precautionary Statements Appendix D.
6.6 Product Identifier
Product identifier should be used on the label 6.6.1 and product identifier should be used on the Material Safety Data Sheet is consistent. If a
Substance or mixture included in the "Model Regulations", the United Nations should use the correct shipping name on the package.
6.6.2 The label should include the chemical name of the substance. For mixtures or alloys, acute toxicity, skin or respiratory sensitization, or specific target
When organ toxicity appear on the label should include the chemical composition of these may cause dangerous of all ingredients or alloying elements on the label. the Lord
Authorities may require listed on the label may cause chemical names of all ingredients or alloying elements mixture or alloy of risk.
6.7 Supplier Identification
The substance or mixture should be provided on the label the name of the manufacturer or supplier, address and telephone number.
6.8 Examples of metallic corrosion labels see Appendix E.
Appendix A
(Informative)
Decision logic and guidance
A.1 metal corrosion decision logic
Figure A.1 according to decision logic of classification.
Decision logic in Figure A.1 metal corrosion
A.2 Guidance
Corrosion rate according to GB/T 21621 Test Method. The metal used for the test consists of the following materials.
a) For the test steels, steel type.
GB/T in 700 Q235B or
GB/T in 700 Q235D
b) For testing of aluminum, the aluminum type. non-coated type 7075-T6 or AZ5GU-T6.
NOTE. If the first test on either steel or aluminum indicates, acceptance test of the substance or mixture is corrosive, it is no longer test on the other metal.
Appendix B
(Normative)
Allocation of label elements
Metallic corrosion assigned label elements are shown in Table B.1.
Allocation Table B.1 metal corrosion Label elements
Category 1 - - - Notes
caveat
It may be corrosive to metals
In the "Model Regulations", the
1) graphic logo color.
Symbol (corrosion). Black
background.
Upper half. white
Lower half. black with white box
Digital 8. White
2) the figure 8 GB 6944-2012 in Class 8.
3) The minimum size of the graphic symbol for the carriage of goods 100mm × 100mm.
NOTE. If a substance or mixture classified as metal corrosion, but the skin and/or eyes when non-corrosive, competent authorities may choose to allow the final state
Is packaged for metal corrosion products hazard pictograms omitted on the label for consumer use of the substance or mixture.
Appendix C
(Normative)
Metal corrosion classification criteria and labeling elements
Metal corrosion category and label elements are shown in Table C.1.
Table C.1 metal corrosion category and label elements
Hazard category Criteria label elements
Test temperature of 55 ℃ in steel or aluminum surfaces
Corrosion rates in excess of 6.25mm/Year
Graphical symbols
Signal word Warning
Hazard statement May be corrosive to metals
Appendix D
(Informative)
Metal corrosion hazard statements and precautionary statements
D.1 Overview
D.1.1 This appendix provides information on how to use consistent with GHS hazard statements and precautionary statements for the metal corrosion, metal corrosion lists
Hazard category for each hazard class and hazard statements and precautionary statements, see GB 13690.
Coding D.1.2 hazard statements
Coding D.1.2.1 hazard statements see GHS Annex 3.
D.1.2.2 Each Hazard statements are assigned a unique alphanumerical code which consists of one letter and three numbers, specific
as follows.
a) letter "H" (for "hazard statement");
b) the first number, part number represents a different risk of setting dangerous within the meaning of the type described, as follows.
--- "2" for physical hazards;
--- "3" for health hazards;
--- "4" for environmental hazards;
c) After two numbers, the sequence number corresponding to the dangerous substance or mixture caused by intrinsic properties, such as. the explosive (code 200 to
210), flammability (codes 220-230), and the like.
D.1.2.3 Unless otherwise specified, all assigned hazard statements should appear on the label. Government authorities may require hazard statements in
Sequence tag appears. In addition, the combination of two or dangerous when the instructions provided above hazard statements, government authorities may specify,
Whether the combined hazard statement or the corresponding individual instructions written to the tag, or/supplier discretion of the manufacturer.
D.1.3 Precautionary statements should be sent with the harmonized hazard communication elements (pictograms, signal words and hazard statements) together meet the requirements marked on the label.
Additional supplemental information, such as instructions for use, may also b...